A combined experimental and computational study to decipher complexity in the asymmetric hydrogenation of imines with Ru catalysts bearing atropisomerizable ligands
نویسندگان
چکیده
RuCl2(P–OP)(N–N) complexes containing an atropisomerizable phosphine–phosphite and a chiral diamine are effective catalyst precursors for the asymmetric hydrogenation of N-aryl imines following outer-sphere mechanism.
منابع مشابه
Asymmetric catalytic hydrogenation. Design of new Ru catalysts and chiral ligands: from laboratory to industrial applications.
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ژورنال
عنوان ژورنال: Catalysis Science & Technology
سال: 2021
ISSN: ['2044-4761', '2044-4753']
DOI: https://doi.org/10.1039/d0cy02390f